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Quality Control in Production Of Biodiesel.

The European standard EN 14214 specifies requirements and test methods for marketed and delivered fatty acid methyl esters (FAME) to be used either as automotive fuel at 100% concentration, or as an extender for automotive fuel for diesel engines.

STANDARD REQUIREMENTS OF EN 14214

Density.

Density increases with a decrease in chain length and unsaturation. This can impact on fuel consumption as fuel introduced into the combustion chamber is determined volumetrically.

Viscosity.

Increase in viscosity results in poor atomization and incomplete combustion which leads to coking of injector tips. Viscosity decreases with unsaturation, but increases markedly with contamination by mono, di or tri glycerides.

Glycerides.

High glyceride content implies low conversion to ester and deposit formation on injectors and valves.

Ester content.

This is measured using gas chromatography and is restricted to ester and deposit falling within the C14 - C24 range. It is ultimately a test for reaction conversion.

Methanol Content.

Methanol can be removed from FAME by washing. High methanol contents pose safety risks due to its very low flash point.

Acid Value.

Acid value is a measure of mineral acids and free fatty acids. High fuels acidity is linked with corrosion and engine deposits.

Iodine Value.

Iodine number is a measure of total unsaturation within the FAME product. High iodine is related to polymerisation of fuels, leading to injector fouling.

Centane Number.

This serves as a measure of ignition quality. Fuels with low centane number show an increase in emissions due to incomplete combustion.

Water Content.

Free water promotes biological growth and the reserves reaction turning bio diesel to free fatty acids.
The entire Biodiesel we manufacture is produced to the European standard En14214.
Certificates of analysis are available for each batch produced. 

Testing Equipment.

Water content is measured with Karl Fischer titration to ensure that the Biodiesel complies with EN14214, and is below 500mg/kg.

Dexter biofuels

 

 

 

 

 

 

www.mt.com/titration

 

Test Frequency of Test Limits Min Max Equipment
Ester Content Each Batch 96.5   Gas Chromatography
Methanol Content Each Batch   0.2% Gas Chromatography
Ester Content Each Batch   0.8% Gas Chromatography
Glycerol Each Batch   0.25% Gas Chromatography
Density Each Batch 860kg/m3 900 kg/m3 Hydrometer
Viscosity Each Batch 3.5mm 2/5 5mm 2/5 Calibrated Cup
Acid Value Each Batch   0.5mg KOH/g Titrometric
Iodine Value Each Batch   120g Iodine/100g Titrometric
Water Content Each Batch   500mg/kg Karl Fisher Titration Method
Flash Point Periodically 120 Degrees C   Rapid Equilibrium Closed Cup
Oxidation Stability Periodically 6 Hours   Conductivity
Determination of ignition quality of Diesel Fuels Periodically 51   Cetane Engine method
Corrosiveness to Copper Periodically Class 1   Copper strip method
Group I Metals Periodically   5mg/kg Atomic Absorption
Group II Metals Periodically   5mg/kg Optical Emission Spectral Analysis
Sulphur Content Periodically   10mg/kg Ultraviolet Fluorescent Method.
Carbon Residue Periodically   0.3% Micro Method.
Sulphated Ash Periodically   0.02% Furnace
Contamination in Middle Distillates. Periodically   24mg/kg Membrane Filter
Linolenic Acid Methyl Ester. Periodically   12%

Gas Chromatography

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